The f_getfree gets number of the free clusters.
FRESULT f_getfree ( DWORD* Clusters // Pointer to the variable to store number of free clusters. );
The f_getfree gets number of free clusters on the drive. The FatFs.sects_clust is indicating number of sectors per cluster, so that the free space in unit of byte can be calcurated with this.
    DWORD clust;
    // Get free clusters
    res = f_getfree(&clust);
    if (res) die(res);
    // Get free bytes
    printf("%lu bytes available on the disk.\n", clust * FatFs->sects_clust * 512);